Tuesday, January 1, 2019
Algal Biomass
In addition to that, ingress to ampere- indorse dioxide and pee atomic calculate 18ssential. Even though micro algae female genitals produce in the figurehead of saline water, saucily water is needed in a raceway pond transcription to compensate for the evaporativeloss dep remnanting on the wind velocity, crease temperature, and humidity level of thelocation. Temperature is an important instalment in biomass cultivation.Most algaegrow purify in warmer climates ranging from 25-40?. Tropical locations with auniformly warm temperature passim the year (Chisti, 2016), can act as perfectlocations for algaculture as the temperature doesnt baffle to be monitored at in tout ensembletimes, and the algae can adapt to local conditions.There atomic number 18 however some drawbacks trance utilise raceway pond dodges, thatrender them sometimes ineffective.Since, vitamin C dioxide is fearfulctd to acceleratethe mathematical product of microalgae, an collecting of oxygen ca n act as a hindrance tothe figure out. There is no known mechanism in a raceway pond, that helps curb thisaccumulation of oxygen. Peak sunshine hours during the day can hamper with thephotosynthesis, as the level of oxygen may gain to up to 3 times of the levelin saturate water. For this reason, smaller raceway ponds achieve better resultsthan queen-sizer ponds with respect to oxygen removal, and in turn better productivity.Another set off with raceways is the contamination due to exposure to rain, sprinkle andother debris. Smaller ponds may be hardened inside, except that cant be said for bouffantrponds. Filtration can help inhibit infestations and contamination of the ponds, only thatis an dear(predicate) process.The achievement damage of biomass with raceways is considered to be the leastexpensive option.The cost of a pond depends on the cause of facility it is built in,plastic lie earthen raceways atomic number 18 the least expensive re quotations with their totalcost of construction amounting to be most $70,000 per hect be, whereasponds envelop in greenhouses or covered facilities are to a greater extent expensive as theyprotect from contamination. Raceways require least amount of crownwork investmentand wherefore remain the system of choice, despite their let loose productivity anddrawbacks.Photo-bioreactors (PBRs)A photo-bioreactor is a closed equipment which provides a viewledenvironment and enables proud productivity of algae.PBRs curb all the problems thatare faced in raceways ponds, deal one C dioxide supply, temperature, optimaloxygen levels, pH levels etc. There are two types of photo-bioreactors- flat-plate andand tubular. Both PBRs are do of transparent substantives for maximum solar light competency absorption. Flat-plate PBRs are suitable for mass cultivation of algae,because gamey photosynthetic efficiencies can be achieved. tubular PBRs aresuitable for outdoor cultivation, and are constructed with each icin g or plastic tubes.Systems covering large areas outdoors, consist of tubes exposed to sunlight and canbe operated either in batches or continuously. Photo-bioreactors usually set out a4water pool as a temperature govern system in order to frustrate the tubes fromoverheating as they act as solar receptors. They also deplete built in fairing systemfor the tubes without stopping outturn.Fundamentally, using photo-bioreactorsare much than advantageous than using raceways for some reasons, analogous cultivation ofalgae chthonic controlled environments resulting in higher(prenominal)(prenominal) productivity, protection fromcontamination, space-saving and larger surface to multitude ratio. However there aresome limitations attached to PBRs the capital cost is real high which is impedingthe construct of microalgae biofuel drudgery, in spite of larger fruit levels.Also, data from the past two decades has shown that the productivity in an enclosePBR is not much higher than that achieved in open-pond cultures.3. Environmental Limitations of Microalgae CultivationAs with all large master products, wide case microalgae biofuel productioncould own diverse environmental impacts. Water is a critical element of the biofuelproduction processes, in twain raceway-ponds and PBRs.With the current sphericalwater crisis, using large amounts of fresh water to compensate for evaporation inopen ponds or to cool PBRs, renders the system economically un operable. seawater orbrackish water may be use in these functions, but assume to be filtered in order toprevent infestation of bacteria, and contamination. Recirculating water is mavinalternative to curb the usage of water, but that has risks of virus infestations, and theresidues of foregoingly destroyed algae cells.Filtration systems are expensive, andfactor in with the lack of cost intensity level of these systems.Most microalgae production farms have to be rigid close to the equator inorder to ensure high levels of production due to the uniformity of the climate, andadequate amount of solar radiation. Another factor is the type of prop up and terrain thefarm is located in, for instance to install a large raceway pond, a comparatively flat land isrequired. The addition of nutrients and fertilisers equal nitrogen and phosphorus is alsoessential for algaculture.The amount of nutrients and fertilisers to be usedadditionally depends on the s anoint porosity and permeableness of the land. algalcultivation requires a tummy of fertilisers to make up for the compensation for dodo fuels.Researching and budgeting nutrients and fertilisers is a aboriginal concern in research and teaching of microalgae cultivation.Algal cultivation requires usage of dodo fuels continuously in a plethora ofways, ranging from electricity spending during cultivation and natural natural gas used todry the algae for production. In PBRs, the temperature control for cooling the pipesfrom overheating increases the use of fogey fuels. This use of fogy fuels in algaebiofuel production is paradoxical to the cause and a dire need to optimise the systemto minimise the energy usage is established.That being said, microalgae cultivationfaces a anatomy of environmental challenges, coming from the location to the type of5algae. Energy conservation and water circumspection are two of the main challengesto be conquered to make the system sustainable in the future.4. Cost EffectivenessThe cost of algae biofuel production is essential to establish to know howsustainable this system can be in the future. The cost of biofuel production dependson a variety of factors, much(prenominal) as the the fork out of the biomass, geographical location, oil colourcontent, scale of production systems etc.Presently, microalgae biofuel production isstill more expensive than normal diesel fuels because of the on-going R&D, and theambiguity of current knowledge. Chisti in 2007 approximated the cost of produc tionof algal-oils from a PBR with an annual production capacity of 10,000 tons per yearand estimated the cost of $2.80 per litre, considering the oil content to be 30% in thealgae used. This estimation is exclusive of the algal oil to biodiesel conversion costs,logistics, marketing costs and taxes. repayable to these high costs of algal-fuel, the ut nighimportance during research should be given to cost-saving itself, in an attempt tomake biofuel from microalgae cheap enough to be commercialised in the nearfuture.Open pond systems would ideally be the nigh economically viable way tocultivate microalgae biofuel, but not without its set of intrinsic disadvantagesdiscussed forward in this research paper.As the engineering gets increasinglyadvanced, the cost factor multiplies as well(p) making the entire process a lot lesseconomical than what was sticked with first hand. Improved yield of biomass andnutrient oils (or lipids) would make the production costs gloaming rapidly.Moreove r, to reduce the production costs alternative ways to manage energy andwater consumption have to be devised, a alter design for PBRs is necessary.Substitutes for fresh water like wastewater and flue gases can bear to lowercosts of production.Biofuel ProductionThe rapid growth of environmental pollution by the usage of formulaicfossil fuels has sparked a lot of concern globally. The research and development foralternative fuels is one of the principal focuses for every arena in an attempt for asustainable and promising future on this planet for all generations. mixed optionsare available to us to help us make this shift, however to find a sustainable methodwhich is as promising as it is economically viable is a global challenge. electric currently,biomass derived fuels seem to be the most upbeat runway.Various ways of harvesting algae have been discussed in this paper, the next tone istypically to process the algae in a series of steps which differ from species to6species. On e of the most important approaches in biomass production isHydrothermal Liquefaction or HTL.5.1 Hydrothermal LiquefactionHydrothermal Liquefaction employes a continuous process that subjectsharvested besotted algae to high temperatures and pressures (Elliot, 2013).Convertingsolid biomass to liquid fuels is not a spontaneous process. The liquid fuels derivedfrom fossil fuels on a large scale took thousands of years to change biomass tocrude oil and gas. In stupefy day, there are many modern conversion technologies toobtain liquefied fuels from unhomogeneous(a) biomasses, these conversion technologies canfundamentally be classified into biochemical and thermochemical conversion.Biochemical mass usually has low energy density, high moisture content and doesnot have a very syrupy somatogenic form.Thermochemical conversions in comparisonare much more viscous as they are converted at very high temperatures in highpressures in the presence of catalysts that make the conversions much more rapid.Simply, Hydrothermal Liquefaction is the thermochemical conversion of biomassinto liquid fuels by touch in a hot, pressurized environment for satisfactory time tobreak depressed into solid bio polymeric social organisation to mainly liquid components(Gollakota, 2017).Microalgae is, amongst all possible biomass sources, the most efficientand reliable source of askew biomass due to its high photosynthetic efficiency,maximum production levels, and its rapid growth in almost all environments. Overthe years, many thermochemical conversions have made their way, and while eachhas their pros and cons, HTL has come a long way as one of the most appropriateprocesses to tackle thermochemical conversion of wet biomass.Many scientists overthe years have make extensive research pertaining to the development ofhydrothermal liquefaction, such(prenominal) as Beckmann and Elliott who studied the propertiesof oil obtained from HTL of biomass, and gave all important(p) in amazes with respect to the kindof catalysts and other parameters are pertinent to the HTL process to ensure epoch-making productivity.5.2 Process MechanismCurrently, the knowledge close HTL process mechanisms is qualitative andneeds a lot more space for research.The mechanism comprises of three studysteps depolymerisation, decomposition and recombination. The chemistry behind allthese processes is very intricate as the biomass is a complex mixture ofcarbohydrates, proteins, oils etc. Each operative mechanism of hydrothermalliquefaction is discussed below.5.2.1 Depolymerisation7In this process the macromolecules of the biomass are dissolves through theirphysical and chemical properties.Depolymerisation makes it easier for the biomassto overcome its natural qualities and start behaving like fossil fuels. It mimics thegeological processes, that are convolute in the production of conventional fossil fuels.The process first grounds the feedstock material into small chunks and mixes it withwa ter, if the feedstock is fry. This mixture is then put into a pressure vessel reactionchamber where it is heat at a constant tidy sum at a temperature of 250?, themixture is held in these conditions for approximately 15 minutes at the end of whichthe pressure is released and most of the water is turn off.The resultant concoctionconsists of crude hydrocarbons and solid minerals. The minerals are removed andthe hydrocarbons are sent to the second stage.The disadvantage of this process is that it only breaks down long molecularchains into shorter ones, this implies that smaller molecules like carbon dioxide ormethane cannot be broken down foster by depolymerisation.Decomposition or vapourThe second stage of hydrothermal liquefaction involves the loss of the watermolecule, the carbon dioxide molecule and the acid content. Water at high pressuresand temperatures breaks down the hydrogen bonded structure of celluloses and inturn forms glucose monomers. This is how HTL provides an alt ernative processroute from microalgae biofuels to hydrocarbon liquid fuels.5.2.3 RecombinationThis is the last step in HTL which is reverse of the two previous processesbecause of the absence of the hydrogen compound.The free radicals are largelyavailable which in turn recombine or repolymerise to form high molecular weight unit charcompounds.5.3 Hydrothermal Liquefaction of MicroalgaeThe main advantage of using HTL for microalgae is that it doesntrequire the predrying of feedstock, however ensuring a relatively high production. Theprocess of HTL employ to microalgae is similar to treating cellulose but with a fewdifferences, the major one being treating wed feedstock as opposed to dryfeedstock.One of the principally researched issues that ordain ensure high productivityis a high lipid yield, which is necessary to convert microalgae into biodiesel. Theeffect of significant variables, such as temperature, pressure, volume, biomassconcentration and compositions of algae, catalysts et al. is still under research.During hydrothermal liquefaction of microalgae, a rational heat prudence system8must be put in rump that ensures energy efficiency and separation of the endproduct.Current Situation Future ViabilityIn present day, pertaining to all the advantages and disadvantages of HTL,there is sufficient proof that HTL has capability to become a commercialisedtechnology in the future.Biofuels produced using hydrothermal liquefaction are absent of carbon, thisimplies that there are no carbon emissions produced when the biofuel is burnt.Materials like algae use photosynthesis to grow, and consequently use the carbondioxide al correct present in the atmosphere.The carbon relief produced by biofuelsis exponentially lower than what is already being experienced by conventional fossilfuels. Hydrothermal Liquefaction is a clean process, which doesnt harm theenvironment by producing harmful gases like ammonia or sulphur. If the technologyis mastered, HTL can pave the way for clean algal biofuels globally, although thereare still a number of challenges to be overcome.ConclusionThe cultivation and production of microalgae biofuels is swiftly developing andis receiving attention and bread and butter from global leaders. The rapid increase in worldpopulation, and hence the energy demand is a siren call to devise an alternativeenergy source. Microalgaes respective(a) qualities make it a promising path to tread onwhen it comes to biofuels. There are various ways to derive biofuels from algae aswe maxim in this paper, and also many challenges attached with them.Bio-oil obtainedfrom various processes suffers from various drawbacks such as a high oxygencontent, instability etc, therefore an optimal technique to efficiently convert biomassto biofuel should be researched in order to be able to commercialise the use ofbiofuels in the near future. Making biofuels economically viable in the future is a bigchallenge in itself.Even though, photo-bioreactors promise a satiny future in terms ofbiofuel cultivation, the strike costs attached from cultivating the biofuel to makingit market ready and selling it are still instead high. These high costs of biofuels ascompared to conventional fossil fuels are what render them unready forcommercialisation. However, even with theoretical development and research, abright future for microalgae fossil fuels presents itself.
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